Matrix isolation study of D2Te and H2Te molecules in solid argon

Article abstract of DOI:10.1063/1.440918

A careful synthesis of H2Te and D2Te and their isolation in solid argon are reported.Rare gas metrix isolated molecules of H2Te and D2Te were studied using Moessbauer spectroscopy.The gaseous species were identified using mass spectrometry.Moessbauer parameters were analyzed using extended Hueckel calculations.A good agreement between the experimental and the calculated value of the quadrupole splitting requires a smaller quadrupole moment for the excited state of 125Te then that reported in the literature.A 10percent increase in the QS for D2Te is explained as due to the enhancement of <1/r³> caused by a slight contraction of the D-Te bond.

Full text of DOI:10.1063/1.440918

Matrix isolation study of D2Te and H2Te molecules in solid argon
P. A. Montano, H. M. Nagarathna, D. Newlin, and G. W. Stewart
Citation: The Journal of Chemical Physics 74, 5558 (1981); doi: 10.1063/1.440918
View online: http://dx.doi.org/10.1063/1.440918
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/74/10?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
132.236.27.111 On: Wed, 17 Dec 2014 18:53:19

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.236.27.111 On: Wed, 17 Dec 2014 18:53:19
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.236.27.111 On: Wed, 17 Dec 2014 18:53:19
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
32.236.27.111 On: Wed, 17 Dec 2014 18:53:19
1