Interconversion of (η3-Allyl)(η4-conjugated-diene) (η5-cyclopentadienyl)zirconium and -hafnium Stereoisomers. Evidence for the Simultaneous Rearrangement of Diene and Allyl Ligands

DOI: 10.1002/hlca.19890720804

Source and publish data:

Helvetica Chimica Acta p. 1676 - 1689 (1989)

Update date:2022-08-28

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Authors:

Sontag, Christoph

Berke, Heinz

Sarter, Christian

Erker, Gerhard

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Article abstract of DOI:10.1002/hlca.19890720804

Reaction of (η³-allyl)(cyclopentadienyl)zirconium(4+) chloride with (2,3-dimethylbutadiene)magnesium or (2-phenylbutadiene)magnesium gave the (η³-allyl)(η⁴-conjugated diene)(cyclopentadienyl)zirconium complexes 3c and 3d,

Full text of DOI:10.1002/hlca.19890720804

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