Cs2CO3 promoted O-alkylation of alcohols for the preparation of mixed alkyl carbonates

DOI: 10.1016/S0040-4039(99)00084-2

Source and publish data:

Tetrahedron Letters p. 1847 - 1850 (1999)

Update date:2022-08-30

Topics:

Authors:

Chu Chu

Dueno Dueno

Kyung Woon Jung

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Article abstract of DOI:10.1016/S0040-4039(99)00084-2

The presence of cesium carbonate and tetrabutylammonium iodide (TBAI) facilitated efficient O-alkylation of alcohols with alkyl halides, giving rise to the exclusive formation of mixed alkyl carbonates. The cesium effect was also examined comparatively with other alkali carbonates.

Full text of DOI:10.1016/S0040-4039(99)00084-2

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