Lithium Iodide Promoted Rearrangement of Double Activated Alkenylcyclopropanes to Cyclopentenes or 1,3-Dienes

DOI: 10.1016/0040-4039(91)80047-A

Source and publish data:

Tetrahedron Letters p. 4591 - 4594 (1991)

Update date:2022-08-03

Topics:

Authors:

Kasatkin, Aleksander N.

Kulak, Aleksander N.

Tolstikov, Genrikh A.

Shitikova, Olga V.

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Article abstract of DOI:10.1016/0040-4039(91)80047-A

Heating of bicyclic alkenylcyclopropanes 2a-g in DMF with LiI results in good yields of cyclopentenes or conjugated dienes depending on a substrate structure. Key words: 1-ethoxycarbonyl-4-methyl-6-alkenyl-3-oxabicyclo<3.1.0>hexan-2-ones: 1-ethoxycarbonyl

Full text of DOI:10.1016/0040-4039(91)80047-A

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