Journal of molecular catalysis p. L9-L11 (1989)
Update date:2022-08-29
Topics:
Keller
Reaction of the [Mo(NO)2]2+ moiety with a suitable ligands is a very convenient method to synthesize different dinitrosylmolybdenum complexes. It was also applied for the synthesis of a new compound of empirical formula Mo(NO)2(O2CMe)2. The reaction of catalyst precursor with EtAlCl2 was spectroscopically examined (IR in the v(NO) region). Reagent concentrations were as in the metathesis reaction. The reaction between Mo(NO)2(O2CMe)2 and EtAlCl2 is accompanied by liberation of ethane. During the stable period of the system (decrease in intensity of the bands v(NO) < 1%) one molar equivalent (vs. precursor concentration) of ethane evolved.
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