Tetrahedron Letters p. 4569 - 4572 (1996)
Update date:2022-08-29
Topics:
Garcia Ruano, Jose L.
Martin Castro, Ana M.
Rodriguez Ramos, Jesus H.
Conditions to achieve reductive hydrolysis of β-cyanosulfoxides into their corresponding β-sulfenylamides are reported. The anchimeric assistance of the sulfinyl oxygen in the hydrolysis of the cyano group is proposed to explain the mild condition required to achieve it and several proofs supporting this assumption are indicated. From these results a new mild method to transform sulfoxides into sulfides has been developed.
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