Journal of Organic Chemistry p. 2207 - 2208 (1992)
Update date:2022-08-29
Topics:
Chatgilialoglu, C.
Guarini, A.
Guerrini, A.
Seconi, G.
Tris(trimethylsilyl)silane reacts spontaneously at ambient temperature with molecular oxygen to form (Me3SiO)2Si(H)SiMe3 in high yield.The reaction proceeds via a free-radical chain mechanism and probably involves three consecutive unimolecular processes which are unknown in the literature.
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