KOMPLEXKATALYSE. XVI. UEBER DIE REAKTION VON TRICHLORO-MONONITROSYL-MOLYBDAEN(II)- UND DICHLORO-DINITROSYL-MOLYBDAEN(0)-VERBINDUNGEN MIT EtAlCl2. NACHWEIS EINES Mo0Cl(NO)-KOMPLEXFRAGMENTS IN DEN KATALYSATORLOESUNGEN FUER DIE OLEFINMETATHESE

Article abstract of DOI:10.1016/S0022-328X(00)99141-1

The formation of an unstable Mo⁰Cl(NO)-containing complex in the reaction of trichloronitrosylmolybdenum(II) or dichlorodinitrosylmolybdenum(0) complexes MoCl3(NO)(OPPh3)2 or MoCl2(NO)2(PPh3)2 with EtAlCl2 has been proved by trapping experiment