Carbon-Carbon Bond Formation promoted by Electrophiles and the Mechanism of the Fischer-Tropsch Reaction

DOI: 10.1039/c39830000166

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Journal of the Chemical Society. Chemical communications p. 166 - 167 (1983)

Update date:2022-08-29

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Authors:

Nutton, Andrew

Miguel, Amelio Vazquez de

Isobe, Kiyoshi

Maitlis, Peter M.

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Article abstract of DOI:10.1039/c39830000166

Decomposition of trans-<(C5Me5RhMe)2(μ-CH2)2> takes place at 20 deg C in the presence of 1-electron oxidisers to give methane, ethylene, and notably propylene, by coupling of C₁ ligands (thermally the same reactions only occur at 250 deg C); th

Full text of DOI:10.1039/c39830000166

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