PREPARATION OF ALLYLIC ALCOHOLS BY ALKENE TRANSFER FROM ZIRCONIUM TO ZINC

DOI: 10.1016/S0040-4039(00)77062-6

Source and publish data:

Tetrahedron Letters p. 5197 - 5200 (1994)

Update date:2022-08-10

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Authors:

Wipf, Peter

Xu, Wenjing

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Article abstract of DOI:10.1016/S0040-4039(00)77062-6

Transmetalation of alkenyl zirconocenes 2 to the corresponding organozinc compounds 3 occurs rapidly and at low temperature in the presence of stoichiometric amounts of commercially available dimethyl- or diethylzinc.Subsequent addition of aldehydes provides an in situ protocol for the conversion of alkynes 1 into allylic alcohols 5 in good to excellent yields.

Full text of DOI:10.1016/S0040-4039(00)77062-6

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