REACTIONS OF BIMETALLIC GROUP VI COMPLEXES II. PHOSPHINE AND PHOSPHITE DERIVATIVES; LIGAND TRANSFER AND OXIDATIVE DECARBONYLATION; THE CRYSTAL STRUCTURE OF

Article abstract of DOI:10.1016/S0022-328X(00)98804-1

Triphenylphosphine and trimethylphosphite react with (M, M'=Mo, W) (II) to give <(C5H5)(OC)2LM(μ-SMe)M'(CO)5> which on heating revert to II.On prolonged heating is formed. <(C5H5)(OC)3W(μ-SMe)W(CO)5> reacts with I2 to give fo