Stereoselective preparation of phosphine oxides via a 2,3-sigmatropic shift of allylic diphenylphosphinites

DOI: 10.1016/S0040-4039(99)00952-1

Source and publish data:

Tetrahedron Letters p. 4981 - 4984 (1999)

Update date:2022-08-28

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Authors:

Demay, Stephane

Harms, Klaus

Knochel, Paul

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Article abstract of DOI:10.1016/S0040-4039(99)00952-1

The thermic rearrangement of various chiral or racemic allylic diphenylphosphinites to allylic phosphine oxides has been applied for the preparation of several chiral diphosphine oxides of interest for asymmetric catalysis.

Full text of DOI:10.1016/S0040-4039(99)00952-1

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