Direct and high yield syntheses of Re2(CO)10 and Re(CO)5 Cl by sodium reduction of K2ReCl6 under CO

DOI: 10.1016/S0022-328X(97)00466-X

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 122 (1997)

Update date:2022-08-12

Topics:

Authors:

Klahn, A. Hugo

Oelckers, Beatriz

Toro, Adriana

Godoy, Fernando

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Article abstract of DOI:10.1016/S0022-328X(97)00466-X

A convenient procedure for the synthesis of the rhenium carbonyls Re₂(CO)₁₀ and Re(CO)₅ Cl is reported. Sodium reduction of the easily available K₂ReCl₆, under CO presssure (2400 psi, 280°C (external temperature), THF as solvent) affords Re₂(CO)₁₀ and Re(CO)₅Cl in 81% and 86% isolated yield, respectively. Depending on the hexachlororhenate:Na ratio, either carbonyl derivative can be obtained almost exclusively.

Full text of DOI:10.1016/S0022-328X(97)00466-X

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