Journal of Organometallic Chemistry p. 121 - 122 (1997)
Update date:2022-08-12
Topics:
Klahn, A. Hugo
Oelckers, Beatriz
Toro, Adriana
Godoy, Fernando
A convenient procedure for the synthesis of the rhenium carbonyls Re2(CO)10 and Re(CO)5 Cl is reported. Sodium reduction of the easily available K2ReCl6, under CO presssure (2400 psi, 280°C (external temperature), THF as solvent) affords Re2(CO)10 and Re(CO)5Cl in 81% and 86% isolated yield, respectively. Depending on the hexachlororhenate:Na ratio, either carbonyl derivative can be obtained almost exclusively.
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