Direct and high yield syntheses of Re2(CO)10 and Re(CO)5 Cl by sodium reduction of K2ReCl6 under CO

DOI: 10.1016/S0022-328X(97)00466-X

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 122 (1997)

Update date:2022-08-12

Topics:

Authors:

Klahn, A. Hugo

Oelckers, Beatriz

Toro, Adriana

Godoy, Fernando

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(97)00466-X

A convenient procedure for the synthesis of the rhenium carbonyls Re₂(CO)₁₀ and Re(CO)₅ Cl is reported. Sodium reduction of the easily available K₂ReCl₆, under CO presssure (2400 psi, 280°C (external temperature), THF as solvent) affords Re₂(CO)₁₀ and Re(CO)₅Cl in 81% and 86% isolated yield, respectively. Depending on the hexachlororhenate:Na ratio, either carbonyl derivative can be obtained almost exclusively.

Full text of DOI:10.1016/S0022-328X(97)00466-X

Products guided by the article

Product name:RHENIUM PENTACARBONYL CHLORIDE

Cas No:14099-01-5

R&D Labs maybe for 14099-01-5

Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Tai zhou world Pharm & Chem Co., Ltd

Contact:+86-576-85301198

Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Jinan YouCheng Pharmatech Co.,Ltd

Contact:+86-18653163205

Address:No.750, Shunhua Road, University Science Park, High-tech Zone, Jinan City
Clearsynth Labs Limited

Contact:+91 - 22 - 26355700

Address:17, Lotus Business Park, Andheri West

Relevant to this article

Potential applications of BPFP1 in Bcl-2 protein quantification, carcinoma cell visualization, cell sorting and early cancer diagnosis

Doi:10.1016/j.ejmech.2021.113725
(2021)
Triplet acetylenes as synthetic equivalents of 1,2-bicarbenes: Phantom n,π* state controls reactivity in triplet photocycloaddition

Doi:10.1021/ja043803l
(2005)
Potential of supported copper and potassium oxide catalysts in the combustion of carbonaceous particles

Doi:10.1023/B:KICA.0000038089.98976.95
(2004)
Energy Transfer Dynamics of Formate Decomposition on Cu(110)

Doi:10.1002/anie.201611342
(2017)
Sphaeropsidones, phytotoxic dimedone methyl ethers produced by diplodia cupressi: A structure - Activity relationship study

Doi:10.1021/np100837r
(2011)
Selective and Sequential Aminolysis of Benzotrifuranone: Synergism of Electronic Effects and Ring Strain Gradient

Doi:10.1021/acs.joc.6b01867
(2016)

Article Doi