
Tetrahedron p. 3955 - 3966 (1989)
Update date:2022-08-10
Topics:
Antelo, J.M.
Arce, F.
Casal, D.
Rodriguez, P.
Varela, A.
The kinetics of the decomposition of N-chlorodiethanolamine in water were studied over the range pH 6.55-12.01.Its coefficient of absorption in water at various pH and its protonation constant are reported, and the mechanism of its formation and decomposition is discussed.Comparison of the stabilities of various N-chloroamines shows that the OH group of N-chloroalcoholamines makes them less stable than other N-chloramines and that the mechanism by which they react differs from that of aliphatic N-chloramines.
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