FRAGMENTATION OF (η5-C5H5)Fe(CO)(PPh3)(COCH2COR) COMPLEXES TO THE CATION 5-C5H5)Fe(CO)2(PPh3)>+

DOI: 10.1016/S0022-328X(00)98563-2

Source and publish data:

Journal of Organometallic Chemistry p. C51 - C53 (1983)

Update date:2022-08-24

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Authors:

Davies, Stephen G.

Watts, Oliver

Aktogu, Nurgun

Felkin, Hugh

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Article abstract of DOI:10.1016/S0022-328X(00)98563-2

The unstable iron complexes (η⁵-C5H5)Fe(CO)(PPh3)(COCH2COR) (R = H, Me, Ph, OEt) undergo facile fragmentation with carbon-carbon bond cleavage to generate the iron carbonyl cation <(η⁵-C5H5)Fe(CO)2(PPh3)>⁺ and the correspo

Full text of DOI:10.1016/S0022-328X(00)98563-2

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