Journal of the Chemical Society. Chemical communications p. 715 - 716 (1994)
Update date:2022-08-11
Topics:
Bartoli, Giuseppe
Cimarelli, Cristina
Marcantoni, Enrico
Palmieri, Gianni
Petrini, Marino
A stereoselective synthesis of α,β-unsaturated ketones by direct addition of Grignard reagents to β-enamino ketones, mediated by dry cerium(III) chloride, is described and a trans relationship between the introduced framework and the carbonyl group is predominantly observed.
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