Oxidative Desulfurization-Fluorination of Methyl Arenedithiocarboxylates. A Convenient Synthesis of Trifluoromethylated Aromatic Compounds

DOI: 10.1246/cl.1992.827

Source and publish data:

Chemistry Letters p. 827 - 830 (1992)

Update date:2022-08-16

Topics:

Authors:

Kuroboshi, Manabu

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.827

Trifluoromethyl-substituted aromatic compounds were obtained by oxidative desulfurization-fluorination reaction of methyl arenedithiocarboxylates using n-Bu4N⁺H2F3^- and 1,3-dibromo-5,5-dimethylhydantoin (DBH).Use of N-bromosuccinimide or N-iodosuccinimide instead of DBH afforded difluoro(methylthio)methyl-substituted aromatics.

Full text of DOI:10.1246/cl.1992.827

Products guided by the article

Product name:Benzene, 1-(octyloxy)-4-(trifluoromethyl)-

Cas No:142011-18-5

R&D Labs maybe for 142011-18-5

Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
JIN TAN CHENG'EN CHEMICAL CO.,LTD.

Contact:86-519-82116250

Address:NO.102，village Dongfang，conomic development zone
Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province

Relevant to this article

Water-based conditions for the microscale parallel synthesis of bicyclic lactams

Doi:10.1016/j.tetlet.2012.11.082
(2013)
Synthesis of N-acetyl-3,3a,4,8b- and -1,3a,4,8b-tetrahydrocyclopenta[b] indoles from N- and 2-(cyclopent-2-en-1-yl)anilines

Doi:10.1134/S1070428012120093
(2012)
Synthesis and reactivity of new niobocene hydride-stibine and hydride-stilbene complexes. X-ray crystal structure of [Nb(η⁵- C₅H₄SiMe₃)₂(H)(trans -η²-C,C-PhCH=CHPh)]

Doi:10.1021/om301171j
(2013)
The natural polypropionate-derived esters of the mollusc Onchidium sp.

Doi:10.1021/jo00043a018
(1992)
Aluminum complexes of tridentate amine biphenolate ligands containing distinct N-alkyls: Synthesis and catalytic ring-opening polymerization

Doi:10.1002/jccs.201200559
(2013)
Synthesis of unsymmetrical mono- and bissquaramides with (3-aminopropyl)triethoxysilane (APTES) or dopamine moieties

Doi:10.1055/s-0032-1317546
(2012)

Article Doi