Chemistry Letters p. 827 - 830 (1992)
Update date:2022-08-16
Topics:
Kuroboshi, Manabu
Hiyama, Tamejiro
Trifluoromethyl-substituted aromatic compounds were obtained by oxidative desulfurization-fluorination reaction of methyl arenedithiocarboxylates using n-Bu4N+H2F3- and 1,3-dibromo-5,5-dimethylhydantoin (DBH).Use of N-bromosuccinimide or N-iodosuccinimide instead of DBH afforded difluoro(methylthio)methyl-substituted aromatics.
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