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PleaseRd So Cn oA t da vd aj un s ct ems argins
DOI: 10.1039/C6RA00093B
Journal Name
ARTICLE
using TMSCN catalyzed by a Ti(IV) salen complex. In the
present protocol we have disclosed the first and efficient
enantioselective transformation to synthesis β-nitronitrile
containing all-carbon quaternary stereogenic centers bearing a
trifluoromethyl group with very good enantioselectivity (up to
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99%). The product β-nitronitrile was conveniently transformed
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Acknowledgements
CSIR–CSMCRI communication no. 111/2015. Authors are
thankful to CSIR for SRF, CSIR Network Project on Catalysis and
DST, New Delhi for Project (SR/S1/IC-24/2013) on Catalysis for
financial assistance. Ajay Jakhar is also thankful to AcSIR for
Ph.D. registration and “Analytical Discipline and Centralized
Instrumental Facilities” for providing instrumentation facilities.
Bajaj, ChemCatChem, 2014, 6, 2656.
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