Journal of the Chemical Society. Chemical communications p. 1995 - 1996 (1995)
Update date:2022-08-17
Topics:
Boas, Ulrik
Jakobsen, Mogens Havsteen
Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate) 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.
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