Journal of the Chemical Society. Chemical communications p. 1244 - 1245 (1984)
Update date:2022-08-10
Topics:
Sullivan, B. Patrick
Meyer, Thomas J.
The reactive organometallic trifluoromethanesulphonato (CF3SO3-) complex fac-Re(bpy)(CO)3CF3SO3 (bpy = 2,2'-bipyridine) has been used as a basis for the synthesis of the series of complexes fac-Re(bpy)(CO)3X (X = H, O2CH, and O2COH) all of which are involved in the reduction of CO2; the hydrido complex has been found to undergo a slow thermal reaction with CO2 to give the formato complex, a reaction which is greatly enhanced by visible light.
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