Journal of the Chemical Society. Chemical communications p. 949 - 951 (1992)
Update date:2022-08-25
Topics:
Baldovi, Maria V.
Corma, Avelino
Fornes, Vicente
Garcia, Hermenegildo
Martinez, Agustin
Primo, Jaime
The rearrangement of the cyclic ethylene acetal of 2-bromopropiophenone to 2-hydroxyethyl 2-phenylpropanoate is catalysed by zinc exchanged Y zeolites with higher activity than the conventional ZnCl2; hydrolysis of the acetal moiety owing to the Broensted acid sites is one of the major side reactions, while the competitive formation of 5-methyl-6-phenyl-2,3-dihydro-1,4-dioxine increases with the softness of the Lewis acid centres.
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