Tetrahedron p. 9419 - 9426 (1996)
Update date:2022-08-16
Topics:
Fujita, Yukihiro
Otera, Junzo
Fukuzumi, Shunichi
The highly diastereoselective Mukaiyama-Michael reaction has been realized by use of O,S-ketene silyl acetals. Of special importance in this reaction is the effective tuning of the stereochemical course simply by changing the double bond geometry of ketene silyl acetals. Thus, both syn- and anti-Michael adducts can be obtained on the synthetically useful levels of stereochemical purity.
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