Please Gd roe en no tC ha ed mj u iss tt r my argins
Page 8 of 9
ARTICLE
Journal Name
1
the energies of benzylamine-graphene system, graphene and the
isolated benzylamine molecule respectively. The adsorption
energies were corrected using D3 correction method.
Macharia and S. L. Suib, Appl. Catal. B: Environ., 2019, 249,
DOI: 10.1039/D0GC02040K
3
2.
1
1
1
1 X. Jia, J. Ma, F. Xia, M. Gao, J. Gao and J. Xu, Nat. Commun.,
019, 10, 2338.
2
2 H. Huang, J. Huang, Y.-M. Liu, H.-Y. He, Y. Cao and K.-N. Fan,
Green Chem., 2012, 14, 930.
Conclusions
3 C. Su, M. Acik, K. Takai, J. Lu, S.-J. Hao, Y. Zheng, P. Wu, Q.
Bao, T. Enoki, Y. J. Chabal and K. P. Loh, Nat. Commun., 2012,
In summary, F-doped hierarchical carbon nanomaterials were
synthesized by a facile, cost-effective and green synthetic
3
, 1298.
strategy, in which an F-containing dye pollutant was adsorbed 14 X.-H. Li and M. Antonietti, Angew. Chem. Int. Ed., 2013, 52,
4
572.
by LDH and converted to a high-value carbocatalyst. The two-
dimensional space and surface confinements of LDH not only
create an ultrahigh surface area but also guarantee the high
content of F in the samples. For oxidative self-coupling of
1
1
5 H. Wang, X. Zheng, H. Chen, K. Yan, Z. Zhu and S. Yang,
Chem. Commun., 2014, 50, 7517.
6 B. Chen, L. Wang, W. Dai, S. Shang, Y. Lv, and S. Gao, ACS
Catal., 2015, 5, 2788.
primary amines to imines, the low catalyst loading, high 17 B. Chen, S. Shang, L. Wang, Y. Zhang, and S. Gao, Chem.
Commun., 2016, 52, 481.
reaction rate and high activity in the ambient atmosphere
were achieved by the as-prepared FNSHC-700. Furthermore,
FNSHC-700 shows excellent performance in mass production
and recyclability. The origins of the catalytic activity of FNSHC-
1
1
8 X. Wang and Y. Li, J. Mater. Chem. A, 2016, 4, 5247.
9 I.-M. Chung and M. Gopiraman, React. Kinet., Mech. Catal.,
2
017, 122, 205.
2
0 D. Wang and E. Mejía, ChemistrySelect, 2017, 2, 3381.
7
00 were identified. DFT calculations revealed that CF
2
-doped 21 L.-B. Lv, S.-Z. Yang, W.-J. Feng, W.-Y. Ke, B. Zhang, Z.-D. Jiang,
H.-H. Wang, J. Su, X.-H. Li and J.-S. Chen, ChemCatChem,
018, 10, 5331.
FNSHC-700 possesses the optimal active sites and showed the
strongest adsorption of benzylamine. This work highlights a
promising approach to design and synthesize heteroatoms-
doped carbon catalysts for a variety of reactions and energy
applications.
2
2
2
2
2
2 P. Yang, J. Zhang, D. Liu, M. Liu, H. Zhang, P. Zhao and C.
Zhang, Microporous Mesoporous Mater., 2018, 266, 198.
3 K. Wang, P. Jiang, M. Yang, P. Ma, J. Qin, X. Huang, L. Ma and
R. Li, Green Chem., 2019, 21, 2448.
4 J. Ye, K. Ni, J. Liu, G. Chen, M. Ikram and Y. Zhu,
ChemCatChem, 2018, 10, 259.
5 Y. Zhai, M. Chu, C. Xie, F. Huang, C. Zhang, Y. Zhang, H. Liu, H.
Wang and Y. Gao, ACS Sustainable Chem. Eng., 2018, 6,
17410.
Conflicts of interest
There are no conflicts to declare.
2
2
6 Y. Li, S. Shang, L. Wang, Y. Lv, J. Niu and S. Gao, Chem.
Commun., 2019, 55, 12251.
7 F. Yang, X. Fan, C. Wang, W. Yang, L. Hou, X. Xu, A. Feng, S.
Dong, K. Chen, Y. Wang and Y. Li, Carbon, 2017, 121, 443.
8 B. Chen, L. Wang and S. Gao, ACS Catal., 2015, 5, 5851.
9 F. Wang, S. Song, K. Li, J. Li, J. Pan, S. Yao, X. Ge, J. Feng, X.
Wang and H. Zhang, Adv. Mater., 2016, 28, 10679.
0 S. Yang, L. Peng, P. Huang, X. Wang, Y. Sun, C. Cao and W.
Song, Angew. Chem. Int. Ed., 2016, 55, 4016.
Acknowledgements
2
2
The financial supports from National Natural Science
Foundation of China (Grant No. 21672076, 21971077) are
gratefully acknowledged. The authors thank the facility
support of the Analytical and Testing Center at Huazhong
3
University of Science and Technology for all related 31 X. Sun, Y. Zhang, P. Song, J. Pan, L. Zhuang, W. Xu and W.
Xing, ACS Catal., 2013, 3, 1726.
measurements.
3
2 G. Panomsuwan, N. Saito and T. Ishizaki, J. Mater. Chem. A,
2
015, 3, 9972.
3
3
3 J. Zhang and L. Dai, Angew. Chem. Int. Ed., 2016, 55, 13296.
4 F. Pan, B. Li, X. Xiang, G. Wang and Y. Li, ACS Catal., 2019, 9,
2124.
References
1
2
3
4
5
6
7
8
9
M. Tamura and K. Tomishige, Angew. Chem. Int. Ed., 2015,
4, 864.
S. Chakraborty, G. Leitus and D. Milstein, Angew. Chem. Int.
Ed., 2017, 56, 2074.
H. Zhang, C. Wu, W. Wang, J. Bu, F. Zhou, B. Zhang and Q.
Zhang, Appl. Catal. B: Environ., 2018, 227, 209.
S. Furukawa, A. Suga and T. Komatsu, ACS Catal., 2015, 5,
5
35 J. Zhou, J. Lian, L. Hou, J. Zhang, H. Gou, M. Xia, Y. Zhao, T. A.
Strobel, L. Tao and F. Gao, Nat. Commun., 2015, 6, 8503.
36 J. Lu, C. Wang, H. Yu, S. Gong, G. Xia, P. Jiang, P. Xu, K. Yang
and Q. Chen, Adv. Funct. Mater., 2019, 29, 1906126.
37 Y. Chen, Y. Li, F. Yao, C. Peng, C. Cao, Y. Feng and W. Feng,
Sustain. Energy Fuels, 2019, 3, 2237.
38 M. Park, I.-Y. Jeon, J. Ryu, H. Jang, J.-B. Back and J. Cho, Nano
Energy, 2016, 26, 233.
39 H. An, Y. Li, Y. Feng, Y. Cao, C. Cao, P. Long, S. Li and W. Feng,
Chem. Commun., 2018, 54, 2727.
40 J. Xie, X. Zhao, M. Wu, Q. Li, Y. Wang and J. Yao, Angew.
Chem. Int. Ed., 2018, 57, 9640.
41 Z. Ju, S. Zhang, Z. Xing, Q. Zhuang, Y. Qiang and Y. Qian, ACS
Appl. Mater. Interfaces, 2016, 8, 20682.
42 M. Laipan, R. Zhu, Q. Chen, J. Zhu, Y. Xi, G. A. Ayoko and H.
He, J. Hazard. Mater., 2015, 300, 572.
43 M. José dos Reis, F. Silvério, J. Tronto and J. B. Valim, J. Phys.
Chem. Solids, 2004, 65, 487.
1
214.
V. R. Battula, H. Singh, S. Kumar, I. Bala, S. K. Pal and K.
Kailasam, ACS Catal., 2018, 8, 6751.
Y. Xiao, G. Tian, W. Li, Y. Xie, B. Jiang, C. Tian, D. Zhao and H.
Fu, J. Am. Chem. Soc., 2019, 141, 2508.
B. Zhu, M. Lazar, B. G. Trewyn and R. J. Angelici, J. Catal.,
2
008, 260, 1.
X. Qiu, C. Len, R. Luque and Y. Li, ChemSusChem, 2014, 7,
1
684.
S. Biswas, B. Dutta, K. Mullick, C.-H. Kuo, A. S. Poyraz and S.
L. Suib, ACS Catal., 2015, 5, 4394.
8
| J. Name., 2012, 00, 1-3
This journal is © The Royal Society of Chemistry 20xx
Please do not adjust margins