Tetrahedron Letters p. 3785 - 3788 (1997)
Update date:2022-08-25
Topics:
Bartoli, Giuseppe
Bosco, Marcella
Sambri, Letizia
Marcantoni, Enrico
Transmetallation of an α-methyl-β-silyloxy ketone with TiCl4 in toluene affords a cyclic chelation complex which undergoes highly stereoselective alkylation from Grignard reagents at the less hindered side.
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