Carbohydrate Research p. 227 - 236 (1986)
Update date:2022-08-10
Topics:
Smits, Pierre C. C.
Kuster, Ben F. M.
Wiele, Kees van der
Baan, Hessel S. van der
Aldoses and aldonic acids have been oxidised with oxygen and air at 55 deg in water, using Pt/C catalysts.After oxidation of the reducing group, if available, the primary hydroxyl group is preferentially oxidised using an unmodified catalyst.Addition of a lead(II) salt changes the preference dramatically towards oxidation at the position α to the carboxyl group.Provided that oxygen transfer to the liquid phase is carefully controlled in order to prevent deactivation of the catalyst, 2-ketoaldonic acids can be prepared in high yields.
View More
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
Chongqing Kangheyuecheng Pharmaceutical Technology Co., LTD
Contact:86+023-61183015-18725809730
Address:Degan Industrial Park Jiangjin Chongqing City
Wuxi Zuping Food Science And Technology Co.,LTD.
Contact:+86-510-87210822
Address:Guanlin town
Contact:18710867521(wechat)
Address:Rm10516,Galaxy Tech Building #2,No.25 Tangyan Rd,Hi-Tech Zone,Xi'an, China
website:http://www.dulynet.com/
Contact:025-84699383 -8003
Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Doi:10.1007/s10562-019-02998-y
(2020)Doi:10.1134/S1070363216070306
(2016)Doi:10.1246/bcsj.36.899
(1963)Doi:10.1021/acs.jmedchem.0c02152
(2021)Doi:10.1080/00397910802139387
(2008)Doi:10.1021/ja505521k
(2014)
