Synlett p. 758 - 760 (1997)
Update date:2022-08-16
Topics:
Ishihara, Kazuaki
Ishida, Yuji
Nakamura, Shingo
Yamamoto, Hisashi
The LBA which is prepared from tin tetrachloride and optically active binaphthol or its monomethyl ether is a highly effective reagent for the enantioselective protonation of prochiral allyltrimethyltins. The absolute stereochemical selectivity is quite different from that in the protonation of silyl enol ethers which we reported earlier.
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