ASYMMETRIC SYNTHESIS BY CHIRAL COBALT CATALYSTS: HOMOGENEOUS REDUCTION OF KETONES TO OPTICALLY ACTIVE ALCOHOLS

DOI: 10.1016/0022-328X(85)80138-8

Source and publish data:

Journal of Organometallic Chemistry p. C59 - C60 (1985)

Update date:2022-08-25

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Authors:

Massonneau, V.

Maux, P. Le

Simonneaux, G.

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Article abstract of DOI:10.1016/0022-328X(85)80138-8

The hydrogenation of ketones with Co2(CO)6(PR3)2 (PR3 = PPh2-neo-menthyl, PPh2-6-deoxo-1,2.3,4-diisopropylidene D-galactose and PMe2-menthyl)as catalysts gives optically active alcohols in optical yields of 1.6 to 5percent.

Full text of DOI:10.1016/0022-328X(85)80138-8

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