Tetrahedron Asymmetry p. 2189 - 2192 (1997)
Update date:2022-08-11
Topics:
Heggvik, Lindis R.
Fiksdahl, Anne
The enantiospecific transformation of the optically active amines 1 and 2 via the nucleophilic substitution of the N,N-dimesylimides (1Ms, 2Ms) and the N,N-dinosylimides (1Ns, 2Ns) to the corresponding alcohols 3 and 4 is reported. Different oxygen nucleophiles were used and the alcohol products were enriched with 74-95% of the enantiomer formed by inversion of configuration.
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