1,2-Methanoadamantane: A Molecule with a Twist Bent ? Bond

DOI: 10.1021/jo00095a004

Source and publish data:

Journal of Organic Chemistry p. 4362 - 4363 (1994)

Update date:2022-08-10

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Authors:

Mlinaric-Majerski, Kata

Kaselj, Mira

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Article abstract of DOI:10.1021/jo00095a004

The reaction of 1-(chloromethyl)-2-bromoadamantane with sodium leads to ring closure to the hitherto unknown 1,2-methanoadamantane (1).Reactivity studies of 1 provide strong evidence for the existence of a twist bent ? bond.

Full text of DOI:10.1021/jo00095a004

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