Preparation of a mixed-metal ketenylidene complex from Mn(CO)5(CX3) (X = Cl, Br)

DOI: 10.1021/om00139a041

Source and publish data:

Organometallics p. 1750 - 1752 (1986)

Update date:2022-08-17

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Authors:

Crespi, Ann M.

Shriver, Duward F.

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Article abstract of DOI:10.1021/om00139a041

The reaction of Mn(CO)₅(CBr₃) and [PPN][Co(CO)₄] yields the mixed-metal ketenylidene complex [PPN][MnCO₂(CO)₉(μ₃-CCO)]. The structure of the ketenylidene complex was determined by X-ray crystallography.

Full text of DOI:10.1021/om00139a041

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