Synthesis of acylsilanes via transmetalation of 1-triorganosilyloxyvinyltin derivatives

DOI: 10.1016/0022-328X(92)83451-M

Source and publish data:

Journal of Organometallic Chemistry p. C13 - C18 (1992)

Update date:2022-08-16

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Authors:

Verlhac, Jean-Baptiste

Kwon, HeeAn

Pereyre, Michel

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Article abstract of DOI:10.1016/0022-328X(92)83451-M

Transmetalation of 1-triorganosilyloxyvinyltin derivatives occurs with a reverse Brook rearrangement.Subsequent trapping with various electrophiles affords new acylsilanes.

Full text of DOI:10.1016/0022-328X(92)83451-M

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