Russian Chemical Bulletin p. 1868 - 1872 (1998)
Update date:2022-08-11
Topics:
Zakharova
Kudryavtseva
Konovalov
The alkaline hydrolysis of O-ethyl O-(p-nitrophenyl) chloromethylphosphonate catalyzed by the micelles of cetylpyridinium bromide is inhibited on addition of KCl, KBr, or sodium salicylate (NaSal). This is caused by both a decrease in the nucleophile concentration in micelles owing to a reduction in the surface potential and a change in the micellar structure and properties.
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