Tetrahedron Letters p. 7353 - 7356 (1998)
Update date:2022-08-11
Topics:
Watanabe, Shizue
Kobayashi, Yukari
Arai, Takayoshi
Sasai, Hiroaki
Bougauchi, Masahiro
Shibasaki, Masakatsu
The Yb-BINOL-complex-catalyzed enantioselective epoxidation of α,β- unsaturated ketones (enones) was greatly improved by addition of a small amount of water (ca. 5 equiv to Yb). Optimized conditions and a plausible mechanism of the role of water and molec
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