Tetrahedron Letters p. 3699 - 3702 (1993)
Update date:2022-08-04
Topics:
Steffan, Robert J.
Kearny, Robert M.
Hu, David C.
Failli, Amedeo A.
Skotnicki, Jerauld S.
et al.
The base catalyzed degradation of rapamycin was re-examined and a sequence of steps involving β-elimination, retro-aldol cleavage and benzilic acid rearrangement occur leading to several new products.
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