Journal of the Chemical Society. Chemical communications p. 119 - 120 (1993)
Update date:2022-08-18
Topics:
Fouche, Gerda
Horak, R. Martinus
Meth-Cohn, Otto
3-Phenyl-2,3-epoxy ketones are transformed using baker's yeast into the corresponding 1,2,3-triols as one pure diastereoisomer (S,S,S and R,R,R) formed by syn ring opening of the epoxide after first reduction of the carbonyl group; the reaction results in the epoxy-oxygen becoming the mid OH group of the triol, implicating enzyme attack at the C-3 in the ring-opening reaction.
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