Inorganic Chemistry p. 1290 - 1293 (1968)
Update date:2022-08-24
Topics:
L'Eplattenier
Calderazzo
The preparation and characterization of Ru(CO)4P(C6H5)3 and Os(CO)4P(C6H5)3 have been accomplished and a new route to the already known disubstituted Ru(CO)3(P(C6H5)3)2 and Os(CO)3(P(C6H5)3)2 has been found. Reaction with molecular hydrogen on some of these triphenylphosphine-substituted carbonyls has led to OsH2(CO)3P(C6H5)3, RuH2(CO)2(P(C6H5)3) 2, and OsH2(CO)2(P(C6H5)3) 2. For the latter two compounds, the nuclear magnetic resonance and infrared spectra indicate an octahedral structure with both hydrogens in a cis position and the triphenylphosphine substituents in trans positions.
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