Canadian Journal of Chemistry p. 234 - 238 (2017)
Update date:2022-08-03
Topics:
Chen, Jun
Sun, Xuxin
Oliver, Allen G.
Wulff, Jeremy E.
Thiele's acid has been resolved for the first time by diastereomeric salt formation with brucine. Determination of absolute stereochemistry was accomplished by X-ray crystallography of the corresponding diester. We anticipate that access to optically resolved Thiele's acid will stimulate its use in a diverse range of applications requiring chiral molecular clefts.
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