Chemistry Letters p. 705 - 708 (1993)
Update date:2022-08-16
Topics:
Victory, Pedro
Borrell, Jose I.
Batllori, Xavier
Teixido, Jordi
Civit, Pau
Alvarez-Larena, Angel
The intramolecular nature of the 1,7-O,O'-acyl migration observed during the column chromatography of the diazonium coupling products of methyl 3-acetoxy-6-hydroxy-2-methoxypentafulvene-1-carboxylate was determined by isotopic labeling and mass spectrometry. A cooperative transportation by the hydrazono group is proposed to explain this fact.
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