Journal of Organometallic Chemistry p. 109 - 120 (1985)
Update date:2022-08-11
Topics:
Chan, T. H.
Koumaglo, K.
Trialkylsilallyl anion is alkylated by alkyl halides to give regio- and strereo-selectively the γ-product with trans-strereochemistry at double bond.The trans-vinylsilanes are transformed strereoselectively to Z-vinyl iodides.Coupling of the vinyl idiodes with organometallic reagents gives Z-alkenes.This approach has been applied to the synthesis of several insect sex pheromones.
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