SILICON IN ORGANIC SYNTHESIS. STREREOSELECTIVE SYNTHESIS OF SOME INSECT SEX PHEROMONES

DOI: 10.1016/0022-328X(85)87361-7

Source and publish data:

Journal of Organometallic Chemistry p. 109 - 120 (1985)

Update date:2022-08-11

Topics:

Authors:

Chan, T. H.

Koumaglo, K.

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Article abstract of DOI:10.1016/0022-328X(85)87361-7

Trialkylsilallyl anion is alkylated by alkyl halides to give regio- and strereo-selectively the γ-product with trans-strereochemistry at double bond.The trans-vinylsilanes are transformed strereoselectively to Z-vinyl iodides.Coupling of the vinyl idiodes with organometallic reagents gives Z-alkenes.This approach has been applied to the synthesis of several insect sex pheromones.

Full text of DOI:10.1016/0022-328X(85)87361-7

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