Journal of the Chemical Society. Chemical communications p. 927 - 929 (1982)
Update date:2022-08-29
Topics:
Yoneda, Fumio
Kuroda, Kazunori
An effective autorecycling system for the biomimetic synthesis of α-amino-acids by the reductive amination of α-keto-acids has been achieved for the first time using 10-aryl-5-deazaflavin, ammonium formate, and formic acid; each mole of the 5-deazaflavin catalyses the reduction, by formic acid, of up to 20 moles of the α-imino-acids formed in situ from the α-keto-acids and ammonium formate.
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