Chemistry Letters p. 735 - 738 (1987)
Update date:2022-08-31
Topics:
Maruyama, Kazuhiro
Katagiri, Toshimasa
In the Grignard reactions with benzil (diketone) and with benzophenone (monoketone) in THF rates of electron transfer and of successive R. transfer from Grignard reagents were determined by direct observations of intermediate radicals.The electron transfer rates from Grignard reagents to ketones are dependent on both the electrochemical properties of Grignard reagents and ketones.
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