Asymmetric Reduction of Ketones with B-(cis-10-Pinanyl)-9-borabicyclononane. Observation of a Change in Enantioselection between Similar Organoborane and Organoaluminium Reagents

DOI: 10.1021/jo00195a059

Source and publish data:

Journal of Organic Chemistry p. 4101 - 4102 (1984)

Update date:2022-08-18

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Authors:

Midland, Mark M.

McLoughlin, Jim I.

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Article abstract of DOI:10.1021/jo00195a059

The title reagent reduces prochiral ketones of moderate steric bulk in modest to good enantiomeric excesses of the S alcohols.The absolute configuration is the opposite of that obtained with a similar organoaluminium reagent.

Full text of DOI:10.1021/jo00195a059

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