Journal of the Chemical Society. Chemical communications p. 206 - 207 (1985)
Update date:2022-08-18
Topics:
Baldwin, Jack E.
Jackson, David A.
Adlington, Robert M.
Rawlings, Bernard J.
Whereas hypochlorite oxidation of 1-amino-cis-<2,3-(2)H2>cyclopropane carboxylic acid yields ethylene with retention of stereochemistry the use of transition metal oxidants, such as copper(II), permanganate, and ferrate ions gives completely scrambled cis- and trans-<1,2-(2)H2>ethylene as is found in the biosynthethic process.
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