Polyhedron p. 1 - 7 (2017)
Update date:2022-08-23
Topics:
Biswas, Sujan
Sarkar, Deblina
Roy, Puspendu
Mondal, Tapan Kumar
The synthesis and characterization of a mixed ligand Ru(II) complex, [Ru(dppp)(L)Cl] (1) (where, dppp?=?bis(diphenylphosphino) propane) is reported. The distorted octahedral geometry of the complex is confirmed by X-ray diffraction method. Cyclic voltammogram in CH3CN exhibits Ru(II)/Ru(III) quasireversible oxidation couple along with reversible azo-bond reductions peaks with reference to Ag/AgCl electrode. The efficiency of the complex towards the transfer hydrogenation of ketones in i-PrOH is examined and an excellent catalytic conversion (90–98%) is observed. The electronic structure and redox properties are well corroborated with the DFT calculations.
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