Conjugate Addition Reactions of Chiral (E)-Crotylsilanes: Application to an Asymmetric Cyclopentane Annulation

DOI: 10.1021/jo00061a001

Source and publish data:

Journal of Organic Chemistry p. 2345 - 2348 (1993)

Update date:2022-08-23

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Authors:

Panek, James S.

Jain, Nareshkumar F.

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Article abstract of DOI:10.1021/jo00061a001

Functionalized (E)-crotylsilanes 1 undergo Lewis acid promoted conjugate addition reactions with α-substituted enals and methyl vinyl ketone 2 to produce tetrasubstituted cyclopentanes 3 with high levels of diastereoselection.The reaction is believed to p

Full text of DOI:10.1021/jo00061a001

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