Journal of Organic Chemistry p. 1597 - 1602 (1981)
Update date:2022-08-11
Topics:
Hargis, J. H.
Mattson, G. A.
The reactions of hexamethylphosphorous triamide and some cyclic analogues with anhydrides, acid chorides, and esters are reported.A mechanism is postulated which involves nucleophilic attack of trivalent phosphorus upon the carbonyl carbon, followed by phosphorane formation and a concerted fragmentation to products.
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