Tetrahedron Letters p. 2867 - 2870 (1997)
Update date:2022-08-11
Topics:
Hikichi, Shinichi
Gao, Yuan
Sato, Fumie
Reaction of 7-, 8- and 9-membered cyclic allylic compounds 2 with (η2propene)Ti(O-i-Pr)2 (1) via an oxidative addition pathway provides the corresponding allylic titanium compounds, which, in turn, react with aldehydes and imines stereoselectively, thus providing an efficient and stereoselective method for synthesizing cycloalkenes having a side chain at the allylic position.
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