3,3'-Bi[cyclohexene]

Base Information

• Chemical Name: 3,3'-Bi[cyclohexene]
• CAS No.: 1541-20-4
• Molecular Formula: C12H18
• Molecular Weight: 162.275
• Hs Code.: 2902199090
• Mol file: 1541-20-4.mol

Synonyms:1,1'-Bi-2-cyclohexenyl-(4CI); 3,3'-Bi-1-cyclohexenyl; 3,3'-Bicyclohexenyl; Bis(2-cyclohexenyl)

Chemical Property of 3,3'-Bi[cyclohexene]

Chemical Property:

• Melting Point: 236.5-237 °C
• Boiling Point: 234°Cat760mmHg
• Flash Point: 72.2°C
• PSA: 0.00000
• Density: 0.937g/cm³
• LogP: 3.69900

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,3'-Bi[cyclohexene]

There total 62 articles about 3,3'-Bi[cyclohexene] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.9%

cyclohexene (110-83-8) → cyclohexenone (930-68-7) + bicyclohexyl-2,2'-diene (1541-20-4) + 3-tert-butylperoxocyclohexene (40648-13-3) + Cyclohex-2-enol (822-67-3)

Guidance literature:

With tert.-butylhydroperoxide; μ-nitrido-bis[tetra(tert-butyl)phthalocyaninatoiron]; In water; acetonitrile; at 60 ℃; for 14h; Reagent/catalyst; Catalytic behavior; Inert atmosphere;

DOI:10.1016/j.molcata.2016.08.013

Reference yield: 49.0%

methanol (67-56-1) + cyclohexene (110-83-8) → cyclohexylcyclohexane (92-51-3) + bicyclohexyl-2,2'-diene (1541-20-4) + 2-cyclohexyl-cyclohexene (1808-09-9) + cyclohexylmethyl alcohol (100-49-2)

Guidance literature:

With europium(III) chloride; In methanol; for 8h; Further byproducts given; Irradiation;

DOI:10.1246/bcsj.59.1195

Reference yield: 49.0%

methanol (67-56-1) + cyclohexene (110-83-8) → cyclohexylcyclohexane (92-51-3) + bicyclohexyl-2,2'-diene (1541-20-4) + 2-cyclohexyl-cyclohexene (1808-09-9) + 3-hydroxymethylcyclohexene (103668-33-3,3309-97-5) + cyclohexylmethyl alcohol (100-49-2)

Guidance literature:

With europium(III) chloride; for 8h; Product distribution; Mechanism; Irradiation; also other alkenes and reaction conditions;

DOI:10.1246/bcsj.59.1195

upstream raw materials:

diacetyl peroxide

cyclohexene

tetrachloromethane

dichloromethane

Downstream raw materials:

cyclohexylcyclohexane

Refernces

• 1、 Hikichi, Shinichi,Gao, Yuan,Sato, Fumie. "Efficient synthesis of 7-, 8- and 9-membered cyclic allyltitanium compounds and their stereoselective addition reaction with aldehydes and imines". . p. 2867 - 2870. Retrieved 1997.
• 2、 Gilbert, J. C.,Luo, T.. "Photochemical Fragmentation of a Methylenecyclopropane". . p. 5237 - 5239. Retrieved 1981.
• 3、 Sidera, Mireia,Fletcher, Stephen P.. "Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides". . p. 5044 - 5047. Retrieved 2015.
• 4、 Pal, Suman,Cotard, Marine,Gérardin, Baptiste,Hoarau, Christophe,Schneider, Cédric. "Cu-Catalyzed Oxidative Allylic C-H Arylation of Inexpensive Alkenes with (Hetero)Aryl Boronic Acids". supporting information. p. 3130 - 3135. Retrieved 2021/05/05.
• 5、 Sun, Chun-Yi,To, Wai-Pong,Hung, Faan-Fung,Wang, Xin-Long,Su, Zhong-Min,Che, Chi-Ming. "Metal-organic framework composites with luminescent pincer platinum(II) complexes: 3MMLCT emission and photoinduced dehydrogenation catalysis". . p. 2357 - 2364. Retrieved 2018/03/05.