A NOVEL PHOTOCHEMICAL SYNTHESIS OF PYRROLES FROM β-KETOVINYLOGOUS AMIDES

DOI: 10.1016/S0040-4039(00)61542-3

Source and publish data:

Tetrahedron Letters p. 7697 - 7700 (1993)

Update date:2022-08-11

Topics:

Authors:

Winkler, Jeffrey D.

Siegel, Miles G.

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Article abstract of DOI:10.1016/S0040-4039(00)61542-3

Irradiation of β-ketovinylogous amides leads to the formation of 3-acylpyrroles.A mechanistic rationale is offered which involves the recombination of a photochemically generated biradical, followed by transannular condensation to give the observed pyrrole product.

Full text of DOI:10.1016/S0040-4039(00)61542-3

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