Formation and structure of iBu)PPh2-P,P'>2(CO)> - a cage molecule-pair or an ion-pair complex?

DOI: 10.1016/0022-328X(94)80170-3

Source and publish data:

Journal of Organometallic Chemistry p. 223 - 230 (1994)

Update date:2022-08-11

Topics:

Authors:

Zhang, Zheng-Zhi

Yu, Ao Yu, Ao

Xi, Hua-Ping

Wang, Ru-Ji

Wang, Hong-Gen

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Article abstract of DOI:10.1016/0022-328X(94)80170-3

The strong ?-acid ligand Ph2PN(ⁱBu)PPh2 reacts with Co2(CO)5 (1:1) to give Co2<μ-Ph2PN(ⁱBu)PPh2>(μ-CO)2(CO)4 (1); however,when the ratio is 2:1 a novel species iBu)PPh2-P,P'>2(CO)> (2) has been obtained.

Full text of DOI:10.1016/0022-328X(94)80170-3

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